Abstract Carbonaceous porous materials are strong candidates for producing low-cost, lightweight, and sustainable electromagnetic (EM) absorbing materials. This work investigates the production of radar-absorbing materials (RAM) by a simple method. Sustainable carbon xerogel (CX) was synthesized from tannin, a biosourced molecule. CX and commercial carbon nanotube (CNT) were embedded in a silicone matrix at proportions of 10 and 15 wt.% of CX and 0.1 wt.% of CNT to produce flexible composites. The morphology and structure of the carbonaceous materials were evaluated by field-emission scanning electron microscopy (FEG-SEM), Raman spectroscopy, X-ray diffraction (XRD), textural properties by N2 adsorption-desorption isotherms, and mercury porosimetry. The electromagnetic characterization of the composites was analyzed by a vector network analyzer (VNA) in the Ku-band. The results demonstrated that an increased concentration of CX in the composite improved reflection loss reaching -43.19 dB at 13.79 GHz.

ABSTRACT Radar Absorbing Materials (RAMs) are composite materials able to attenuate an incident electromagnetic wave. Usually, RAMs are made of a polymeric matrix and an electromagnetic absorbent filler, such as silicon carbide or carbon black. Several materials have been investigated as potential fillers, aiming to improve the Reflection Loss (RL) and absorption bandwidth broadening. In this paper, a composite made with silicone rubber and biochar was investigated as a sustainable porous carbon made with biomass waste. Five different composites were characterized, composed of 1 - 5 wt.% of biochar in the silicone rubber. Although the RL of pure biochar composites is not significant, it was demonstrated here how a biochar composite can improve the RL of a RAM material when it is applied as a double-layer structure. While the RL of a ferrite-based RAM with 2.0 mm thickness reaches -28 dB, a combination of this RAM with biochar composite reaches ~ -60 dB with the same thickness. The double-layer structure with 2.3 mm thickness can have an absorption bandwidth of 2.95 GHz over the X-band frequency range, and a structure with 2.6 mm thickness can reach a RL of ~ -76 dB. This demonstrates a sustainable, cheaper, and lighter material application (i.e., biochar), which is successfully used in the development of high-efficient electromagnetic shield or sensors.

RESUMO Este trabalho apresenta as propriedades eletromagnéticas de um Material Absorvedor de Radiação Eletromagnética (MARE) feito a partir de Carbeto de Silício (SiC) e Negro de Fumo (NF) como aditivos. O compósito SiC/NF foi produzido utilizando 70 %(m/m) de matriz de silicone, e variando as concentrações do aditivo em 3 %(m/m), 2 %(m/m) e 1 %(m/m) de NF com 27 %(m/m), 28 %(m/m) e 29 %(m/m) de SiC, respectivamente. A estrutura química e a morfologia das partículas de SiC e NF foram analisadas através de espectroscopia Raman e Microscopia Eletrônica de Varredura (MEV). As propriedades dielétricas dos MAREs foram obtidas por meio do analisador de rede vetorial na faixa de frequência de 12,4 a 18,0 GHz. Os resultados de refletividade mostraram que o compósito SiC/NF com 1 %(m/m) de NF apresentou a melhor absorção de radiação eletromagnética, chegando a -47,9 dB em 16,8 GHz com uma amostra de aproximadamente 5,5 mm de espessura.

ABSTRACT Este trabalho apresenta as propriedades eletromagnéticas de um Material Absorvedor de Radiação Eletromagnética (MARE) feito a partir de Carbeto de Silício (SiC) e Negro de Fumo (NF) como aditivos. O compósito SiC/NF foi produzido utilizando 70 %(m/m) de matriz de silicone, e variando as concentrações do aditivo em 3 %(m/m), 2 %(m/m) e 1 %(m/m) de NF com 27 %(m/m), 28 %(m/m) e 29 %(m/m) de SiC, respectivamente. A estrutura química e a morfologia das partículas de SiC e NF foram analisadas através de espectroscopia Raman e Microscopia Eletrônica de Varredura (MEV). As propriedades dielétricas dos MAREs foram obtidas por meio do analisador de rede vetorial na faixa de frequência de 12,4 a 18,0 GHz. Os resultados de refletividade mostraram que o compósito SiC/NF com 1 %(m/m) de NF apresentou a melhor absorção de radiação eletromagnética, chegando a -47,9 dB em 16,8 GHz com uma amostra de aproximadamente 5,5 mm de espessura.

In this manuscript, the electromagnetic wave absorption properties of sustainable porous carbon composites were evaluated over the X-band frequency range (8.2 - 12.4 GHz). The porous carbon material was made from the byproduct of cellulose production and was used as additive on the development of radar absorbing material (RAM) composites. These porous carbon materials have different characteristics, such as porosity size (180 µm < Ø1 < 250 µm and 425 µm < Ø2 < 500 µm) and particle size (ϕ1 < 250 µm and 250 µm < ϕ2 < 425 µm). Composite materials were also studied as frequency selective surface (FSS) structures. It was shown how complex permittivity and reflection loss (RL) can be manipulated over the frequency range using FSS structure. While regular RAM presented RL of 19 dB at ~11.8 GHz, FSS structure presented a RL of 19 dB shifted to 12.4 GHz regarding the same carbon porous material (with particles between 250 and 425 µm and porosity between 180 and 250 µm). It was demonstrated here the potential use of sustainable porous carbon as RAM, and how FSS structure can be used to tune the frequency of the RL maximum peak.

ABSTRACT The increment of recycling of steel using electric arc furnace and the tendency to coat of steel products with zinc, in order to prevent corrosion, has increased the proportion of galvanized scrap used worldwide in the recent years. Approximately 10 to 20 Kg/t of cast steel is generated in casting arcs. These collected dusts electric arc furnace (EAF dust) contains iron, zinc, lead, and cadmium. Mainly in the form of oxides and their wastes are considered hazardous typically in countries such as Brazil, U.S., Japan and Germany. It is estimated that from the total of 7.5 million metric tons of EAF dust generated worldwide only 45% is recycled. With Waelz process, the EAF dust can be treated to recover zinc by means of reduction-volatilization-oxidation reactions occurring within the rotary kiln. In this work the thermodynamics of the Waelz process is studied to optimize the recovery of volatiles especially zinc. Kinetic parameters were evaluated trough series of ten experiments, comprise the major process factors such as type of reductants (charcoal and petroleum coke), time (20 – 120 minutes) and temperature (450 - 1150°C). The mechanical behavior of the pellets was evaluated by compressive cold strength and drop tests. Characterization was performed using scanning electron microscopy, microanalysis EDS, X-ray diffraction, X-ray fluorescence, granulometric analysis by laser diffraction, as well as measurements of moisture, bulk density and percentage of volatiles, fixed carbon and ash. The small pellets (10mm) with charcoal used as a reductant, presented a higher compression and higher recovery of volatiles than those with petroleum coke.